2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2

0,4-----------------0,2----------------------------------------0,2

2CH3COOH+CaO->(CH3COO)2Ca+H2O

0,1----------------0,05

n CO2=0,2 mol

=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)

=>%m CaO=12,28%

=>n CaO=0,05 mol

=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)

a)

\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: CaCO₃ + 2CH₃COOH --> (CH₃COO)₂Ca + CO₂ + H₂O

                0,2<---------0,4<------------------------------0,2

=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)

=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)

b)

\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)

PTHH: CaO + 2CH₃COOH --> (CH₃COO)₂Ca + H₂O

            0,05---->0,1

=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)

c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đ),t^o--> CH₃COOC₂H₅ + H₂O

Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH₃COOH

\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)

=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)

C32: 

a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)

PT: \(C+O_2\underrightarrow{t^o}CO_2\)

Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)

b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)

\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO₃ và Na₂CO₃

PT: \(CO_2+NaOH\rightarrow NaHCO_3\)

\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)

⇒ m_NaHCO3 = 0,1.84 = 8,4 (g)

m_Na2CO3 = 0,1.106 = 10,6 (g)

c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)

Lần sau bạn đăng tách câu hỏi ra nhé.

C31:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)

c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)

200ml dung dịch H₂SO₄ loãng.

a) Cu không phản ứng với H₂SO₄ loãng.

Zn  +  H₂SO₄  -->  ZnSO₄  + H₂ 

b) nH₂ = \(\dfrac{1,12}{22,4}\)=0,05 mol => nZn = 0,05 mol

mZn = 0,05.65 = 3,25 gam <=> mCu = 8,5 - 3,25 = 5,25 gam

Chất rắn thu được sau phản ứng chính là Cu không phản ứng = 5,25 gam.

c)

nH₂SO₄ = nH₂ = 0,05 mol 

=> C_H2SO4 = \(\dfrac{n}{V}\)= \(\dfrac{0,05}{0,2}\)= 0,25 M

Hơi muộn nhé, lần sau bạn đăng sớm hơn chứ hầu hết giờ nay mọi người đi ngủ rồi, chúc bạn thi tốt nhé ^^

a) Gọi \(\left\{{}\begin{matrix}n_{MgCO_3}=a\left(mol\right)\\n_{CaCO_3}=b\left(mol\right)\end{matrix}\right.\)

\(n_{CO_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)

PTHH:

MgCO₃ + 2CH₃COOH ---> (CH₃COO)₂Mg + CO₂ + H₂O

a---------->2a-------------------->a----------------->a

CaCO₃ + 2CH₃COOH ---> (CH₃COO)₂Ca + CO₂ + H₂O

b---------->2b------------------>b------------------>b

=> \(\left\{{}\begin{matrix}84a+100b=31,8\\a+b=0,35\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,15\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{MgCO_3}=0,2.84=16,8\left(g\right)\\m_{CaCO_3}=0,15.100=15\left(g\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{16,8}{31,8}.100\%=52,8\%\\\%m_{CaCO_3}=100\%-52,8\%=47,2\%\end{matrix}\right.\)

b) \(V_{dd}=\dfrac{2.0,2+2.0,15}{2}=0,35\left(l\right)\)

c) \(m_{muối}=0,2.142+0,15.158=52,1\left(g\right)\)

\(n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)

\(MgO+2HCl\rightarrow MgCl_2+H_2O\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(0.05..............................0.05\)

\(m_{Mg}=0.05\cdot24=1.2\left(g\right)\)

\(m_{MgO}=9.5-1.2=8.3\left(g\right)\)

\(\%Mg=\dfrac{1.2}{9.5}\cdot100\%=12.63\%\)

\(\%MgO=100-12.63=87.36\%\)

Zn+2HCl->ZnCl2+H2

ZnO+2HCl->ZnCl2+H2O

nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)

mZnO=21.1-13=8.1(g)

nZnO=0.1(mol)

Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)

mHCl=21.9(g)

C%ddHCl=21.9:200*100=10.95%

n muối=0.2+.1=0.3(mol)

m muối=40.8(g)